Graphene, how can we produce it on a larger scale?

November 8, 2022 Gerhard Bauhuis

What is the role of flow control in graphene production?

Graphene can be produced using different methods. One of the most used methods in single-layered graphene product is plasma enhanced chemical vapour deposition (PE-CVD). Flow control devices are being used to dose gases and liquids into the process.
In this blog I would like to share the story of our Spanish distributor, Iberfluid Instruments S.A, who cooperated with the University of Cordoba in research to investigate the opportunities regarding graphene production on a large scale by using a plasma based technique under atmospheric pressure with a Bronkhorst evaporation system.
Let me start by sharing some background information about graphene and flagship funded by the European Commission.

Graphene, how can we produce it on a larger scale?

Graphene Flagship

Funded by the European Commission in 2013, the Graphene Flagship has brought graphene research and innovation from the lab into various commercial applications. The ‘Graphene Flagship’ is a Future and Emerging Technology Flagship by the European Commission. The Graphene Flagship facilitates bringing competencies together as well as cooperation between its partners, trying to accelerate and bring forward the industry acceptance of graphene technologies. Applications for graphene can be found in various areas, like energy and transportation to electronics and biomedicine, influencing our daily lives. The Graphene Flagship serves as technology accelerator, helping Europe to compete with other global markets in research and innovation. With an additional €20 million investment, the European Commission has now funded the creation of an experimental pilot line for graphene-based electronics, opto-electronics, and sensors.

What is graphene?

Graphene can be subdivided in three different types: single-layered, double-layered and multi-layered graphene:

  • Single-layered graphene is the purest form available with with unique characteristics. These characteristics make (single-layered) graphene an attractive product for a large number of applications.
  • Double-layered as well as multi-layered graphene have other (less qualitative) characteristics.
As the number of layers increases, it also becomes increasingly cheaper to produce. In this blog I limit myself to only single-layered graphene, because as of today this type still gives the best result in various research.

Graphene is the world’s first 2D material that consists of only a single atomic layer of carbon; the same material that’s used in diamonds and penciltips. The carbon atoms in graphene are ranked in a hexagon structure. 

Graphene can also be combined with other materials, such as gases and metals, to produce new materials with the abovementioned properties or to improve existing materials. At this point there isn’t a method  available yet to produce graphene on a larger scale against acceptable costs.  However, this is still being researched.

Plasma Enhanced Chemical Vapour Deposition

There are a couple of different methods to produce graphene. One of the most common methods in single-layered graphene production is Plasma Enhanced Chemical Vapour Deposition (PE-CVD). In this method, a mixture of gases - in which at least one gas contains carbon – is heated until a plasma has formed. Mass flow meters and controllers are used in CVD processes to dose gases and liquids accurately.

In PE-CVD the plasma forms a graphene layer on a nickel or copper substrate. Heating takes place in a vacuum, but a more ‘green’ chemical vapour deposition process can be used as well, in which heating takes place under atmospheric pressure. By using Chemical Vapour Deposition large sheets of graphene can be produced.

3D-model structure of Graphene
3D-model structure of graphene

Some of the precursors are liquids that need to be evaporated first, to be used in the CVD process in its gaseous form. It’s very important that the plasma is created with the right proportions and precision. This can be achieved by using highly accurate flow instruments. A deviation in the plasma can cause defects in the graphene layer. Defects can be impurities in the 2D structure that can change the unique properties of the material.

Research for high quality graphene

Our Spanish distributor, Iberfluid Instruments S.A, recently cooperated with the University of Cordoba in research to investigate the opportunities regarding graphene production on a large scale by using a plasma based technique under atmospheric pressure. In this research ethanol was evaporated with the use of Bronkhorst evaporation system, the so-called Controlled Evaporation and Mixing (CEM) system, to form a plasma. With the use of an evaporation system liquids are being evaporated directly to create the right gas for the plasma. A possible setup of such an evaporation system can consist of a CEM system with an additional liquid flow meter (i.e. a Coriolis mass flow meter, from the mini CORI-FLOW series) for ethanol, a gas flow controller (i.e. an EL-FLOW mass flow controller) for argon, which functions as a carrier gas and finally a temperature-controlled control valve or mixing valve.

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Bronkhorst CEM system for research at the University of Cordoba
Bronkhorst CEM system for research at the University of Cordoba

An evaporation system like the Bronkhorst CEM system can deliver excellent performance in terms of stability and accuracy. These properties guarantee a reliable creation of plasma, which eventually leads to higher quality graphene.
In the research document ‘Scalable graphene production from ethanol decomposition by microwave argon plasma torch’ is described why the University of Cordoba (ES) uses the Bronkhorst Controlled Evaporation and Mixing system in the PE-CVD graphene production process.

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Areas of application for graphene

Due to a large amount of unique properties research takes place in numerous areas of application. The main focus is on single-layered and double-layered graphene. For now it seems that single-layered graphene still gives the best results. At the same time the use of so-called flakes has considered account. These flakes are tiny pieces of graphene which can be mixed with another material, such as polymers. The properties of these materials can be improved by adding graphene flakes, which makes graphene widely applicable in different industries. A couple of examples based on single-layered graphene:

  • Water purification: Scientists are currently developing an advanced filtration system based one graphene oxide that is being used to make polluted water drinkable.
  • Medical industry: Since graphene isn’t poisonous for the human body, research is being done to the possibilities to use graphene in medicine transport in the body, by attaching the medicine to the graphene. Graphene also has the properties to prevent bacteria formation, which makes it ideal to use as a coating for implants.

  • Energy industry: Because of the large surface and excellent electrical conduction, graphene could be used in energy storage. The goal is to make graphene batteries more compact than they are now, while increasing the capacity to make it possible to charge batteries within seconds.
  • Textile industry: Graphene could be used to process electronics in textiles, such as effective, efficient and highly accurate sensors. Furthermore, graphene anti-corrosion coatings and conductive inks can be made.
  • Semiconductor industry: Thanks to good electrical and thermal conductivity, graphene offers possibilities to increase the speed and capacity of chips  (for computers and smartphones).

Area of application for graphene: textile industry
Area of application for graphene: textile industry

Would you like more information about the evaporation systems for graphene production?

Contact us or download the research of John Bulmer, scientist at the University of Cambridge, about 'Forecasting continuous carbon nanotube production in the floating catalyst environment'.

Contact us Download the research